Dr Alagiri Kaliyamoorthy
Assistant Professor Grade I (Chemistry)
  +91 (0)471 - 2778050

Publications from IISER

20. "Direct Trideuteromethylation of Sulfenate Anions Generated In Situ from β-Sulfinyl Esters: An Access to Trideuteromethyl Sulfoxides" Fathima Pilathottathil, Sreelakshmi Unnikrishnan, Tamilarasu Murugesan, Alagiri Kaliyamoorthy.*

J. Org. Chem. 2023, 88, 9505–9513..

19. "Palladium-Catalyzed Regioselective C3-Allylic Alkylation of 2-Aryl Imidazopyridines with MBH Carbonates." Tamilarasu Murugesan, Afna Elikkottil, and Alagiri Kaliyamoorthy.*

J. Org. Chem. 2023, 88, 2655–2665.

18. "Heteroarylation of Sulfenate Ions in situ Generated from β-Sulfinyl Esters under Transition-Metal-Free Conditions." Fathima Pilathottathil, Sreelakshmi Unnikrishnan, Alagiri Kaliyamoorthy.*

J. Org. Chem. 2022, 87, 14980−14990.

17. "Regioselective Allenylation and Propargylation of Various para-Quinone Methides Using Alkynyl Azaarenes as Pronucleophile." Amritha Rayaroth, Afna Elikkottil, Chithra Mohan Jayakumari, Kalyanakrishnan Arayil Vennoli, Sivaranjana Reddy Vennapusa, Alagiri Kaliyamoorthy.*

Chem. Commun., 202258, 10671-10674.

16. "Synthesis of Various α-Substituted Alkenyl Sulfoxides from Alkynes and β-Sulfinyl Esters." A. V. Kalyanakrishnan, Arun Joshy, Abhay Kumar Arya, Alagiri Kaliyamoorthy.*

ChemistrySelect, 20216, 14054-14059.

15. "Palladium-Catalyzed Direct C2-Biarylation of Indoles." Tamilarasu Murugesan, Chinraj Sivarajan, Chithra Mohan Jayakumari, Rajat Kumar Singh, Sivaranjana Reddy Vennapusa, Alagiri Kaliyamoorthy.*

J. Org. Chem., 2021, 86, 10838-10851.

14. "Base-promoted 1,6-Conjugate Addition of Alkylazaarenes to para-Quinone Methides." Amritha Rayaroth, Rajat Kumar Singh, A. V. Kalyanakrishnan, Krishna Hari, Alagiri Kaliyamoorthy.*

Org. Biomol. Chem., 202018, 3354-3359.

13. "Synthesis of Various Acylating Agents Directly from Carboxylic Acids." Fathima Pilathottathil, Doppalapudi Vineet Kumar, Alagiri Kaliyamoorthy.*

Synth. Commun. 202050, 1622-1632.

12. "N-Heterocyclic carbene as a Brønsted base catalyst for the amination of naphthol derivatives and alcoholysis of glutaric anhydrides." Jayakrishnan, K.R.; Tamilarasu, M.; Jincy, K.V.; Alagiri Kaliyamoorthy.* 

Tetrahedron Lett. 201960, 151131.

11. "Recent advancements in dehydrogenative cross coupling reactions for C–C bond formation." Varun, B.V.; Dhineshkumar, J.; Bettadapur, K.R.; Siddaraju, Y.; Alagiri, K.; Prabhu, K.R. 

Tetrahedron Lett. 201758, 803-824.

Publications from Postdoc and PhD

10. "Direct Catalytic Asymmetric Mannich-type Reaction of α- and β-Fluorinated Amides." Brewitz, L.; Arteaga, F.; Yin, L.; Alagiri, K.; Kumagai, N.; Shibasaki, M. 

J. Am. Chem. Soc. 2015137, 15929 – 15939.

9. "Iterative Direct Aldol Strategy for Polypropionates: Enantioselective Total Synthesis of (–)-Membrenone A and B." Alagiri, K.; Lin, S.; Kumagai, N.; Shibasaki, M.

Org. Lett. 2014, 16, 5301–5303.

8. "Two Approaches Toward the Formal Total Synthesis of Oseltamivir Phosphate (Tamiflu): Catalytic Enantioselective Three-Component Reaction Strategy and L–Glutamic Acid Strategy." Alagiri, K.; Furutachi, M.; Yamatsugu, K.; Kumagai, N.; Watanabe, T.; Shibasaki, M.

J. Org. Chem. 2013, 78, 4019–4026.

7. "A Versatile C–H Functionalization of Tetrahydroisoquinolines Catalyzed by Iodine at Aerobic Conditions." Dhineshkumar, J.; Lamani, M.; Alagiri, K.; Prabhu, K. R.

Org. Lett. 2013, 15, 1092–1095.

6. "CDC Reactions of N-Aryl Tetrahydroisoquinolines Using Catalytic Amounts of DDQ: C–H Activation Under Aerobic Conditions." Alagiri, K.; Devadig, P.; Prabhu, K. R.

Chem. Eur. J. 2012, 18, 5160 – 5164.

5. "C–H Functionalization of Tertiary Amines by Cross-Dehydrogenative Coupling Reactions: Solvent-Free Synthesis of α-Amino Nitriles and β-Nitro Amines Under Aerobic Condition." Alagiri, K.; Prabhu, K. R.

Org. Biomol. Chem. 2012, 10, 835-842. (Top 10% of most highly cited articles published in 2011-2012)

4. "Molybdenum Trioxide Catalyzed Oxidative Cross-Dehydrogenative Coupling of Benzylic sp3 C–H bonds: Synthesis of α-Aminophosphonates Under Aerobic Condition." Alagiri, K.; Devadig, P.; Prabhu, K. R.

Tetrahedron Lett. 2012, 53, 1456–1459.

3. "An Oxidative Cross-Dehydrogenative-Coupling Reaction in Water Using Molecular Oxygen as the Oxidant: Vanadium Catalyzed Indolation of Tetrahydroisoquinolines." Alagiri, K.; Kumara, G. S. R.; Prabhu, K. R.

Chem. Commun. 2011, 47, 11787–11789.

2. "Catalyst-Free Regio- and Stereospecific Synthesis of β-Sulfonamido Dithiocarbamates: Efficient Ring-Opening Reaction of N-Tosylaziridines by Dialkyldithiocarbamates." Alagiri, K.; Prabhu, K. R.

Chem. Eur. J. 2011, 17, 6922 – 6925.

1. "Efficient Synthesis of Carbonyl Compounds: Oxidation of Azides and Alcohols Catalyzed by Vanadium Pentoxide in Water Using tert-Butylhydroperoxide." Alagiri, K.; Prabhu, K. R.

Tetrahedron 2011, 67, 8544-8551.