Symmetry Breaking Charge Separation in Molecular Constructs for Efficient Light Energy Conversion, E. Sebastian and M.Hariharan*, ACS Energy Lett. 2022, 7, 696-711 (Front Cover).

The Effect of Single Atom Substitution on Structure and Band Gap in Organic Semiconductors, A. T. John, A. Narayanasamy, D. George and M. Hariharan*, Cryst. Growth Des. 2022, 22, 1237-1243.

Tripathy, A. R.; Rizwana, R. A.; Kumar, A.;Yatham, V. R., Photocatalyzed Alkylative Cyclization of 2-Isocyanobiphenyls with Unactivated Alkyl Iodides Org. Biomol. Chem.2022, 20, 3136 - 3144.

V. Athiyarath, M. C. Madhusudhanan, S.Kunnikuruvan, K. M. Sureshan*, Secondary structure tuning of a pseudoprotein between β-meander and α-helical forms in the solid-state (rated as Highly Important Paper).Angew. Chem. Int. Ed., 2022, 61, e202113129

Virtual Issue on Halogen Bonding, M.Hariharan, Cryst. Growth Des. 2022, 22,10.1021/acs.cgd.2c00157.

Yedase, G. S.; Ja, A. K.; Yatham, V. R. Visible-light enabled C(Sp3)–C(Sp2) cross-electrophile coupling via synergistic halogen-atom transfer (XAT) and nickel catalysis J. Org. Chem. 2022,(DOI: 10.1021/acs.joc.2c00251).

Ahmed, M. E.; Boroujeni, M. R.; Ghosh, P.; Greene, C.; Kundu, S.; Bertke, J. A.; Warren, T. H. Electrocatalytic ammonia oxidation by a low-coordinate copper complex. Journal of the American Chemical Society 2022, 144 (46), 21136-21145. DOI:10.1021/jacs.2c07977

Anjana, J.; Muthukrishnan, A.* Effect of local pH change on non-PGM catalysts - a potential-dependent mechanistic analysis of the oxygen reduction reaction. Catalysis Science & Technology 2022, 12 (20), 6246-6255. DOI:10.1039/d2cy01099b

Aparna, R.K.; Mukherjee, S.; Rose, S.S.; Mandal, S.* Silver nanoparticle-incorporated defect-engineered Zr-based metal-organic framework for efficient multicomponent catalytic reactions. Inorganic Chemistry 2022, 61 (41), 16441-16447. DOI:10.1021/acs.inorgchem.2c02542

Ayyappan, R.; Abdalghani, I.; Da Costa, R.; Owen, G.R. Recent developments on the transformation of CO₂ utilising ligand cooperation and related strategies. Dalton Transactions 2022, 51, 11582-11611. DOI:10.1039/D2DT01609E

Ayyappan, R.; Costa, R.C.; Owen, G.R. Recent developments in homogeneous catalysis for the functionalisation of CO₂. In: Patmore, N.J.; Elliott, P.I.P. Organometallic Chemistry: 2022, 44, 23-67. DOI:10.1039/9781839167713

Balakrishnan, V.; Ganguly, A.; Rasappan, R.* Interception of nickel hydride species and its application in multicomponent reactions. Organic Letters 2022, 24 (26), 4804-4809. DOI:10.1021/acs.orglett.2c01862

Bamberger, N.D.; Dyer, D.; Parida, K.N.; El-Assaad, T.; Pursell, D.; McGrath, D.V.; Smeu, M.; Monti, O. Beyond simple structure-function relationships: the interplay of geometry, electronic structure and molecule/electrode coupling in single molecule junctions. Journal of Physical Chemistry C 2022, 126 (15), 6653-6661. DOI:10.1021/acs.jpcc.2c00761

Benny, R.; Sahoo, D.; George, A.; De, S.* Recent advances in fuel-driven molecular switches and machines. ChemistryOpen 2022, 11 (9), e202200128. DOI:10.1002/open.202200128

Biswas, S.; Das, A.K.; Manna, S.S.; Pathak, B.; Mandal, S.* Template-assisted alloying of atom-precise silver nanoclusters: A new approach to generate cluster functionality. Chemical Science 2022, 13 (38), 11394-11404. DOI:10.1039/d2sc04390d

Chakraborty, A.; Sarkar, S.; Kyarikwal, R.; Nag, P.; Vennapusa, S.R.; Mukhopadhyay, S. Piperazine-linked covalent triazine polymer as an efficient platform for the removal of toxic Mercury(II) ions from wastewater. ACS Applied Polymer Materials 2022, 4 (11), 8118-8126. DOI:10.1021/acsapm.2c01085

Chitra, M.J.; Vennapusa, S.R.* Unraveling the T₁ formation in mono-arm styrylbenzene heteroanalogues. Journal of Photochemistry & Photobiology A: Chemistry, 2022, 435, 114327. DOI:10.1016/j.jphotochem.2022.114327

Das, A.K.; Biswas, S.; Manna, S.S.; Pathak, B.; Mandal, S.* An atomically precise silver nanocluster for artificial light-harvesting system through supramolecular functionalization. Chemical Science 2022, 13 (28), 8355-8364. DOI:10.1039/d2sc02786k

Das, A.K.; Biswas, S.; Wani, V.S.; Nair, A.S.; Pathak, B.; Mandal, S.* [Cu₁₈H₃(S-Adm)₁₂(PPh₃)₄Cl₂]: fusion of Platonic and Johnson solids through a Cu(0) center and its photophysical properties. Chemical Science 2022, 13 (25), 7616-7625. DOI:10.1039/d2sc02544b

El-Assaad, T.H.; Zhu, J.; Sebastian, A.; McGrath, D.V.; Neogi, I.*; Parida, K.N.* Dioxiranes: a half-century journey. Organic Chemistry Frontiers 2022, 9 (20), 5675-5725. DOI:10.1039/d2qo01005d

Eledath, A.N.; Poulose, A.E.; Muthukrishnan, A.* O-functionalization of N-doped reduced graphene oxide for topological defect-driven oxygen reduction. ACS Applied Nano Materials 2022, 5 (8), 10528-10536. DOI:10.1021/acsanm.2c01852

Ghosh, P.; Stauffer, M.; Hosseininasab, V.; Kundu, S.; Bertke, J.A.; Cundari, T.R.; Warren, T.H. NO coupling at copper to cis-hyponitrite: N₂O formation via protonation and H-atom transfer. Journal of the American Chemical Society 2022, 144 (33), 15093-15099. DOI:10.1021/jacs.2c04033

Gratious, S.; Karmakar, A.; Kumar, D.; Kundu, S.; Chakraborty, S.; Mandal, S.* Incorporating Au-11 nanoclusters on MoS₂ nanosheet edges for promoting the hydrogen evolution reaction at the interface. Nanoscale 2022, 14 (21), 7919-7926. DOI:10.1039/d2nr00878e

Gratious, S.; Mukherjee, S.; Mandal, S.* Co-reactant-free transformation in atomically precise metal nanoclusters. The Journal of Physical Chemistry Letters 2022, 13 (39), 9014-9027. DOI:10.1021/acs.jpclett.2c02330

Gupta, S.; Arora, S.; Mondal, A.; Stieber, S.C.E.; Gupta, P.*; Kundu, S.* A copper(II)-nitrite complex hydrogen-bonded to a protonated amine in the second-coordination-sphere. European Journal of Inorganic Chemistry 2022, 2022 (15), e202200105. DOI:10.1002/ejic.202200105