Long Alkyl Side-Chains Impede Exciton Interaction in Organic Light Harvesting Crystals
K. Nagarajan, G. Gopan, R. T. Cheriya and M. Hariharan*
ChemComm, 2017, (In Press)
Twisted Perylene Diimides with Tunable Redox Properties for Organic Sodium-Ion Batteries
H. Banda; D. Damien; K. Nagarajan; A. Raj, M. Hariharan* and M. M. Shaijumon*
Adv. Energy Mater. 2017, (In Press)
Self-Assembled Donor-Acceptor Trefoils: Long-Lived Charge Separated State Through Aggregation
A. R. Mallia and M. Hariharan*
J. Phys. Chem. 2017, 121, 4778–4788
Persistent Charge Separated States in Self-Assembled Twisted Non-Symmetric Donor-Acceptor Triad
A. R. Mallia, A. M. Philip, V. Bhat and M. Hariharan*
J. Phys. Chem. 2017, 121, 4765–4777 (Front Cover)
Enhanced Intersystem Crossing in Core-Twisted Aromatics
K. Nagarajan, A. R. Mallia, K. Muraleedharan and M. Hariharan*
Chem. Sci., 2017, 8, 1776-1782 (Outside Back Cover)
V-shaped Oxydiphthalimides: Side Chain Engineering Regulates Crystallisation-Induced Emission Enhancement
G. Gopan, P. S. Salini, S. Deb and M. Hariharan*
CrystEngComm 2017, 19, 419 (Front Cover)
Crystalline Triphenylamine Substituted Arenes: Solid State Packing and Luminescence Properties
A. R. Mallia, R. Ramakrishnan, M. A. Niyas, R. Sethy and M. Hariharan*
CrystEngComm, 2017, 19, 817 - 825
2016
Prolonged Charge Separated States in Twisted Stacks of All-carbon Donor and Acceptor Chromophores
A. M. Philip, A. R. Mallia and M. Hariharan*
J. Phys. Chem. Lett. 2016, 7, 4751–4756 (ACS Liveslides)
On the Origin of Multiexponential Fluorescence Decays from 2-Aminopurine-Labeled Dinucleotides
J. Remington, A. Philip, M. Hariharan and B. Kohler*
J. Chem. Phys. 2016, 145, 155101
Columnar/Lamellar Packing in Cocrystals of Arylbipyridines with Diiodoperfluorobenzene
R. Ramakrishnan, A. R. Mallia, M. A. Niyas, R. Sethy and M. Hariharan*
Cryst. Growth Des. 2016, 10.1021/acs.cgd.6b00968.
Link: http://pubs.acs.org/doi/abs/10.1021/acs.cgd.6b00968
Haloacetylation Driven Transformation of Sandwich Herringbone to Lamellar/Columnar Packing in Pyrene
P. S. Salini, S. K. Rajagopal and M. Hariharan*
Cryst. Growth Des. 2016, 10.1021/acs.cgd.6b00919.
Link: http://pubs.acs.org/doi/abs/10.1021/acs.cgd.6b00919
S•••π, π−π and C−H•••π Contacts Regulate Solid State Fluorescence in Regioisomeric Bisthiazolylpyrenes
S. K. Rajagopal, P. S. Salini and M. Hariharan*
Cryst. Growth Des. 2016, 16, 4567–4573.
Link: http://pubs.acs.org/doi/abs/10.1021/acs.cgd.6b00676
Access to Triplet Excited State in Core-Twisted Perylenediimide
K. Nagarajan, A. R. Mallia, V. S. Reddy and M. Hariharan*
J. Phys. Chem. C 2016, 120, 8443–8450.
Link: http://pubs.acs.org/doi/abs/10.1021/acs.jpcc.6b00755
Nonparallel Stacks of Donor and Acceptor Chromophores Evade Geminate Charge Recombination
A. R. Mallia, P. S. Salini and M. Hariharan*
J. Am. Chem. Soc. 2015, 137, 15604–15607 (Front Cover and JACS Spotlights).
Link: http://pubs.acs.org/doi/full/10.1021/jacs.5b08257
Progressive Acylation of Pyrene Engineers Solid State Packing and Colour via C–H•••H–C, C–H•••O and π-π Interactions
S. K. Rajagopal, A. M. Philip, K. Nagarajan and M. Hariharan*
Chem. Commun. 2014, 50, 8644-8647 (Inside Front Cover).
Link: http://pubs.rsc.org/en/Content/ArticleLanding/2014/CC/c4cc01897d#!divAbstract
Light Harvesting Vesicular Donor-Acceptor Scaffold Limits the Rate of Charge Recombination in the Presence of an Electron Donor
R. T. Cheriya, A. R. Mallia and M. Hariharan*
Energy Environ. Sci. 2014, 7, 1661-1669 (Front Cover; Hot Article).
Link: http://pubs.rsc.org/en/Content/ArticleLanding/2014/EE/c3ee43293a#!divAbstract
Thymine Photodimer Formation in DNA Hairpins. Unusual Conformations Favor (6-4) vs. (2+2) Adducts
M. Hariharan,* K. Siegmund, C. Saurel, M. McCullagh, G. C. Schatz and F. D. Lewis*
Photochem. Photobiol. Sci. 2014, 13, 266-271 (Nick Turro’s Special Issue).
Link: http://pubs.rsc.org/en/Content/ArticleLanding/2014/PP/c3pp50283j#!divAbstract
2013
Thermal Response of DNA Supramolecular Polymers Assembled with Hydrophobic Sticky Ends
M. Hariharan,* Y. Zheng, B. Rybtchinski and F. D. Lewis*
J. Phys. Chem. B, 2013, 117, 14649–14654.
Link: http://pubs.acs.org/doi/abs/10.1021/jp4087078
Perylene Polyimide Based Organic Electrode Materials for Rechargeable Lithium Batteries
P. Sharma, D. Damien, K. Nagarajan, M. M. Shaijumon,* and M. Hariharan*
J. Phys. Chem. Lett., 2013, 4, 3192–3197 (One of the most read articles).
Link: http://pubs.acs.org/doi/abs/10.1021/jz4017359
Breakdown of Exciton Splitting through Electron Donor–Acceptor Interaction: A Caveat for the Application of Exciton Chirality Method in Macromolecules
J. Joy, R. T. Cheriya, K. Nagarajan, A. Shaji, and M. Hariharan*
J. Phys. Chem. C, 2013, 117, 17927–17939.
Link: http://pubs.acs.org/doi/abs/10.1021/jp403431w
Single Component Organic Light-Harvesting Red Luminescent Crystal
R. T. Cheriya, K. Nagarajan and M. Hariharan*
J. Phys. Chem. C, 2013, 117, 3240-3248.
Link: http://pubs.acs.org/doi/abs/10.1021/jp309752x
2012
DNA-Enforced Conformational Restriction of an Atropisomer
R. T. Cheriya, J. Joy, S. K. Rajagopal, K. Nagarajan and M. Hariharan*
J. Phys. Chem. C, 2012, 116, 22631-22636.
Link: http://pubs.acs.org/doi/abs/10.1021/jp308260a
Effect of Temperature on Symmetry Breaking Excited State Charge Separation: Restoration of Symmetry at Elevated Temperature
H. Khandelwal, A. R. Mallia, R. T. Cheriya and M. Hariharan*
Phys. Chem. Chem. Phys., 2012, 15282-15285.
Link: http://pubs.rsc.org/en/content/articlelanding/2012/cp/c2cp42452e#!divAbstract
Energy Transfer in Near-Orthogonally Arranged Chromophores Separated through a Single Bond
R. T. Cheriya, J. Joy, A. P. Alex, A. Shaji, and M. Hariharan*
J. Phys. Chem. C, 2012, 116, 12489–12498.
Link: http://pubs.acs.org/doi/abs/10.1021/jp303406p
Electron Donor–Acceptor Interactions with Flanking Purines Influence the Efficiency of Thymine Photodimerization
Z. Pan, M. Hariharan, J. D. Arkin, A. S. Jalilov, M. McCullagh, G. C. Schatz, and F. D. Lewis*
J. Am. Chem. Soc. 2011, 133, 20793–20798.
Link: http://pubs.acs.org/doi/abs/10.1021/ja205460f
Conformation of a Dodecane DNA Hairpin Linker. Multiple Gauche Bonds Cover the Bases
K. Siegmund, M. Hariharan, and F. D. Lewis*
J. Phys. Chem. B, 2011, 115, 3740–3746.
Link: http://pubs.acs.org/doi/abs/10.1021/jp201188f
2010
Hydrophobic Self-Assembly of a Perylenediimide-Linked DNA Dumbbell into Supramolecular Polymers
P. Neelakandan, Z. Pan, M. Hariharan, Y. Zheng, F. D. Lewis*, H. Weissman, and B. Rybtchinski*
J. Am. Chem. Soc. 2010, 132, 15808-15813.
Link: http://pubs.acs.org/doi/abs/10.1021/ja1076525
Conformational Control of Thymine Photodimerization in Single-Strand and Duplex DNA Containing Locked Nucleic Acid TT Steps
M. Hariharan, M. McCullagh, G. C. Schatz, and F. D. Lewis*
J. Am. Chem. Soc. 2010, 132, 12856-12858.
Link: http://pubs.acs.org/doi/abs/10.1021/ja106203q
Structure and Stability of Alkane-Linked DNA Hairpin Conjugates
M. Hariharan,* K. Siegmund, and F. D. Lewis*
J. Org. Chem. 2010, 75, 6236–6243.
Link: http://pubs.acs.org/doi/abs/10.1021/jo1013299
Perylenediimide-Linked DNA Dumbbells: Long-Distance Electronic Interactions and Hydrophobic Assistance of Base-Pair Melting
M. Hariharan, K. Siegmund, Y. Zheng, H. Long, G. C. Schatz, and F. D. Lewis*
J. Phys. Chem. C 2010, 114, 20466–20471.
Link: http://pubs.acs.org/doi/abs/10.1021/jp1048309
Conformational Control of TT-Dimerization in DNA Hairpins. A Molecular Dynamics Study
M. McCullagh, M. Hariharan, F. D. Lewis*, D. Markovitsi, T. Douki and G. C. Schatz*
J. Phys. Chem. B 2010, 114, 5215-5221.
Link: http://pubs.acs.org/doi/abs/10.1021/jp100983t
Site-selective Interactions: Squaraine Dye-Serum Albumin Complexes with Enhanced Fluorescence and Triplet Yields
V. S. Jisha, K. T. Arun, M. Hariharan and D. Ramaiah*
J. Phys. Chem. B 2010, 114, 5912-5919.
Link: http://pubs.acs.org/doi/abs/10.1021/jp100369x
Direct Evidence on the External Stimuli Induced Dissembly of DNA through Microscopic Techniques
M. Hariharan, E. Kuruvilla and D. Ramaiah*
J. Phys. Chem. Lett. 2010, 1, 834-838.
Link: http://pubs.acs.org/doi/10.1021/jz900447p
Hydrophobic Dimerization and Thermal Dissociation of Perylenediimide-Linked DNA Hairpins
M. Hariharan, Y. Zheng, H. Long, T. A. Zeidan, G. C. Schatz, J. Vura-Weis, M. R. Wasielewski, X. Zuo, D. M. Tiede, and F.. D. Lewis*
J. Am. Chem. Soc. 2009, 131, 5920-5929.
Link: http://pubs.acs.org/doi/abs/10.1021/ja900347t
Sum rules and determination of exciton coupling using absorption and circular dichroism spectra of biological polymers
A. Burin, M. Armbruster, M. Hariharan and F. D. Lewis*
Proc. Natl. Acad. Sci. USA 2009, 106, 989-984.
Link: http://www.pnas.org/content/106/4/989
2008
Photoinduced Charge Separation in Pyrenedicarboxamide-linked DNA Hairpins,
P. Daublain, K. Siegmund, M. Hariharan, J. Vura-Weis, M. R. Wasielewski, F. D. Lewis*, V. Shafirovich*, Q. Wang, M. Raytchev, and Torsten Fiebig*
Photochem. Photobiol. Sci. 2008, 7, 1501-1508.
Link: http://pubs.rsc.org/en/content/articlelanding/2008/pp/b813995d#!divAbstract
Context-Dependent Photodimerization in Isolated Thymine-Thymine Steps in DNA,
M. Hariharan and F. D. Lewis*
J. Am. Chem. Soc. 2008, 130, 11870-11871.
Link: http://pubs.acs.org/doi/abs/10.1021/ja804950j
2007
Encapsulation of Electron Donor-Acceptor Dyads in b-Cyclodextrin Cavity: Unusual Planarization and Enhancement in Rate of Electron Transfer Reaction
M. Hariharan, P. P. Neelakandan and D. Ramaiah*
J. Phys. Chem. B, 2007, 111, 11940-11947.
Link: http://pubs.acs.org/doi/abs/10.1021/jp074643d
Chiral supramolecular assemblies of a squaraine dye in solution and thin films: concentration-, temperature-, and solvent-induced chirality inversion
K. Jyothish, M. Hariharan and D. Ramaiah*
Chem. Eur. J. 2007, 13, 5944-5951.
Link: http://onlinelibrary.wiley.com/wol1/doi/10.1002/chem.200700130/abstract
Selective Recognition of Tryptophan through the Inhibition of Intramolecular Charge-Transfer Interactions in an Aqueous Medium
M. Hariharan, C. K. Suneesh and D. Ramaiah*
Org. Lett. 2007, 9, 417-420.
Link: http://pubs.acs.org/doi/abs/10.1021/ol062636m
2006
Novel Bifunctional Viologen-Linked Pyrene Conjugates: Synthesis and Study of their Interactions with Nucleosides and DNA
M. Hariharan, J. Joseph and D. Ramaiah*
J. Phys. Chem. B 2006, 110, 24678-24686.
Link: http://pubs.acs.org/doi/abs/10.1021/jp063079o
A Supramolecular ON-OFF-ON Fluorescence Assay for Selective Recognition of GTP
P. P. Neelakandan, M. Hariharan and D. Ramaiah*
J. Am. Chem. Soc. 2006, 128, 11334-11335.
Link: http://pubs.acs.org/doi/abs/10.1021/ja062651m
Site-Selective Binding and Dual Mode Recognition of Serum Albumin by a Squaraine Dye
V. S. Jisha, K. T. Arun, M. Hariharan and D. Ramaiah*
J. Am. Chem. Soc. 2006, 128, 6024-6025.
Link: http://pubs.acs.org/doi/abs/10.1021/ja061301x
2005
Synthesis of a Novel Cyclic Donor-Acceptor Conjugate for Selective Recognition of ATP
P. P. Neelakandan, M. Hariharan and D. Ramaiah*
Org. Lett. 2005, 5765-5768.
Link: http://pubs.acs.org/doi/abs/10.1021/ol052246k
LIST OF PATENTS
A Novel Cyclic Donor- Acceptor Conjugate, Process and a Supramolecular Fluorescent Marker Thereof
D. Ramaiah, P. P. Neelakandan and M. Hariharan
IN Patent No. 253901, dated August 31, 2012.