COMPLETE LIST OF PUBLICATIONS

2017

54. Long Alkyl Side-Chains Impede Exciton Interaction in Organic Light Harvesting Crystals
    K. Nagarajan, G. Gopan, R. T. Cheriya and M. Hariharan*
    ChemComm, 2017, (In Press)
53. Twisted Perylene Diimides with Tunable Redox Properties for Organic Sodium-Ion Batteries
    H. Banda; D. Damien; K. Nagarajan; A. Raj, M. Hariharan* and M. M. Shaijumon*
    Adv. Energy Mater. 2017, (In Press)
52. Self-Assembled Donor-Acceptor Trefoils: Long-Lived Charge Separated State Through Aggregation
    A. R. Mallia and M. Hariharan*
    J. Phys. Chem. 2017, 121, 4778–4788
51. Persistent Charge Separated States in Self-Assembled Twisted Non-Symmetric Donor-Acceptor Triad
    A. R. Mallia, A. M. Philip, V. Bhat and M. Hariharan*
    J. Phys. Chem. 2017, 121, 4765–4777 (Front Cover)
50. Enhanced Intersystem Crossing in Core-Twisted Aromatics
    K. Nagarajan, A. R. Mallia, K. Muraleedharan and M. Hariharan*
    Chem. Sci., 2017, 8, 1776-1782 (Outside Back Cover)
49. V-shaped Oxydiphthalimides: Side Chain Engineering Regulates Crystallisation-Induced Emission Enhancement
    G. Gopan, P. S. Salini, S. Deb and M. Hariharan*
    CrystEngComm 2017, 19, 419 (Front Cover)
48. Crystalline Triphenylamine Substituted Arenes: Solid State Packing and Luminescence Properties
    A. R. Mallia, R. Ramakrishnan, M. A. Niyas, R. Sethy and M. Hariharan*
    CrystEngComm, 2017, 19, 817 - 825

2016

47. Prolonged Charge Separated States in Twisted Stacks of All-carbon Donor and Acceptor Chromophores
    A. M. Philip, A. R. Mallia and M. Hariharan*
    J. Phys. Chem. Lett. 2016, 7, 4751–4756 (ACS Liveslides)
46. On the Origin of Multiexponential Fluorescence Decays from 2-Aminopurine-Labeled Dinucleotides
    J. Remington, A. Philip, M. Hariharan and B. Kohler*
    J. Chem. Phys. 2016, 145, 155101
45. Columnar/Lamellar Packing in Cocrystals of Arylbipyridines with Diiodoperfluorobenzene
    R. Ramakrishnan, A. R. Mallia, M. A. Niyas, R. Sethy and M. Hariharan*
    
    Cryst. Growth Des. 2016, 10.1021/acs.cgd.6b00968.
    Link: http://pubs.acs.org/doi/abs/10.1021/acs.cgd.6b00968
44. Haloacetylation Driven Transformation of Sandwich Herringbone to Lamellar/Columnar Packing in Pyrene
    P. S. Salini, S. K. Rajagopal and M. Hariharan*
    
    Cryst. Growth Des. 2016, 10.1021/acs.cgd.6b00919.
    Link: http://pubs.acs.org/doi/abs/10.1021/acs.cgd.6b00919
43. S•••π, π−π and C−H•••π Contacts Regulate Solid State Fluorescence in Regioisomeric Bisthiazolylpyrenes
    S. K. Rajagopal, P. S. Salini and M. Hariharan*
    
    Cryst. Growth Des. 2016, 16, 4567–4573.
    Link: http://pubs.acs.org/doi/abs/10.1021/acs.cgd.6b00676
42. Crystallization Induced Green-Yellow-Orange Emitters Based on Benzoylpyrenes
    S. K. Rajagopal, V. S. Reddy and M. Hariharan*
    
    CrystEngComm 2016, 18, 5089-5094 (Outside Frontispiece).
    Link: http://pubs.rsc.org/en/content/articlelanding/2016/CE/c6ce00610h#!divAbstract
41. Access to Triplet Excited State in Core-Twisted Perylenediimide
    K. Nagarajan, A. R. Mallia, V. S. Reddy and M. Hariharan*
    
    J. Phys. Chem. C 2016, 120, 8443–8450.
    Link: http://pubs.acs.org/doi/abs/10.1021/acs.jpcc.6b00755
40. Crystallization induced enhanced emission in conformational polymorphs of a rotationally flexible molecule
    A. R. Mallia, R. Sethy, V. Bhat and M. Hariharan*
    
    J. Mater. Chem. C 2016, 4, 2931-2935.
    Link: http://pubs.rsc.org/en/content/articlelanding/tc/2016/c5tc03188e#!divAbstract

2015

39. Nonparallel Stacks of Donor and Acceptor Chromophores Evade Geminate Charge Recombination
    A. R. Mallia, P. S. Salini and M. Hariharan*
    
    J. Am. Chem. Soc. 2015, 137, 15604–15607 (Front Cover and JACS Spotlights).
    Link: http://pubs.acs.org/doi/full/10.1021/jacs.5b08257
38. A Polyimide based all-organic sodium ion battery
    H. Banda, D. Damien, K. Nagarajan, M. Hariharan and M. M. Shaijumon*
    
    J. Mater. Chem. A 2015, 3, 10453-10458.
    Link: http://pubs.rsc.org/en/content/articlelanding/2015/ta/c5ta02043c#!divAbstract

2014

37. C–H•••H–C and C–H•••π Contacts Aid Transformation of Dimeric to Monomeric Anthracene in the Solid State
    K. Nagarajan, S. K. Rajagopal and M. Hariharan*
    
    CrystEngComm 2014, 16, 8946-8949.
    Link: http://pubs.rsc.org/en/Content/ArticleLanding/2014/CE/C4CE01278J#!divAbstract
36. Progressive Acylation of Pyrene Engineers Solid State Packing and Colour via C–H•••H–C, C–H•••O and π-π Interactions
    S. K. Rajagopal, A. M. Philip, K. Nagarajan and M. Hariharan*
    
    Chem. Commun. 2014, 50, 8644-8647 (Inside Front Cover).
    Link: http://pubs.rsc.org/en/Content/ArticleLanding/2014/CC/c4cc01897d#!divAbstract
35. Light Harvesting Vesicular Donor-Acceptor Scaffold Limits the Rate of Charge Recombination in the Presence of an Electron Donor
    R. T. Cheriya, A. R. Mallia and M. Hariharan*
    
    Energy Environ. Sci. 2014, 7, 1661-1669 (Front Cover; Hot Article).
    Link: http://pubs.rsc.org/en/Content/ArticleLanding/2014/EE/c3ee43293a#!divAbstract
34. Non-natural G-quadruplex in a Non-natural Environment
    S. K. Rajagopal and M. Hariharan*
    
    Photochem. Photobiol. Sci. 2014, 13, 157-161 (Nick Turro’s Special Issue).
    Link: http://pubs.rsc.org/en/Content/ArticleLanding/2014/PP/c3pp50199j#!divAbstract
33. Thymine Photodimer Formation in DNA Hairpins. Unusual Conformations Favor (6-4) vs. (2+2) Adducts
    M. Hariharan,* K. Siegmund, C. Saurel, M. McCullagh, G. C. Schatz and F. D. Lewis*
    
    Photochem. Photobiol. Sci. 2014, 13, 266-271 (Nick Turro’s Special Issue).
    Link: http://pubs.rsc.org/en/Content/ArticleLanding/2014/PP/c3pp50283j#!divAbstract

2013

32. Thermal Response of DNA Supramolecular Polymers Assembled with Hydrophobic Sticky Ends
    M. Hariharan,* Y. Zheng, B. Rybtchinski and F. D. Lewis*
    
    J. Phys. Chem. B, 2013, 117, 14649–14654.
    Link: http://pubs.acs.org/doi/abs/10.1021/jp4087078
31. Perylene Polyimide Based Organic Electrode Materials for Rechargeable Lithium Batteries
    P. Sharma, D. Damien, K. Nagarajan, M. M. Shaijumon,* and M. Hariharan*
    
    J. Phys. Chem. Lett., 2013, 4, 3192–3197 (One of the most read articles).
    Link: http://pubs.acs.org/doi/abs/10.1021/jz4017359
30. Breakdown of Exciton Splitting through Electron Donor–Acceptor Interaction: A Caveat for the Application of Exciton Chirality Method in Macromolecules
    J. Joy, R. T. Cheriya, K. Nagarajan, A. Shaji, and M. Hariharan*
    
    J. Phys. Chem. C, 2013, 117, 17927–17939.
    Link: http://pubs.acs.org/doi/abs/10.1021/jp403431w
29. Single Component Organic Light-Harvesting Red Luminescent Crystal
    R. T. Cheriya, K. Nagarajan and M. Hariharan*
    
    J. Phys. Chem. C, 2013, 117, 3240-3248.
    Link: http://pubs.acs.org/doi/abs/10.1021/jp309752x

2012

28. DNA-Enforced Conformational Restriction of an Atropisomer
    R. T. Cheriya, J. Joy, S. K. Rajagopal, K. Nagarajan and M. Hariharan*
    
    J. Phys. Chem. C, 2012, 116, 22631-22636.
    Link: http://pubs.acs.org/doi/abs/10.1021/jp308260a
27. Effect of Temperature on Symmetry Breaking Excited State Charge Separation: Restoration of Symmetry at Elevated Temperature
    H. Khandelwal, A. R. Mallia, R. T. Cheriya and M. Hariharan*
    
    Phys. Chem. Chem. Phys., 2012, 15282-15285.
    Link: http://pubs.rsc.org/en/content/articlelanding/2012/cp/c2cp42452e#!divAbstract
26. Energy Transfer in Near-Orthogonally Arranged Chromophores Separated through a Single Bond
    R. T. Cheriya, J. Joy, A. P. Alex, A. Shaji, and M. Hariharan*
    
    J. Phys. Chem. C, 2012, 116, 12489–12498.
    Link: http://pubs.acs.org/doi/abs/10.1021/jp303406p
25. Facially-Selective Thymine-Thymine Photodimerization in TTT Triads
    P. P. Neelakandan, Z. Pan, M. Hariharan and F. D. Lewis*
    
    Photochem. Photobiol. Sci., 2012, 11, 889-892.
    Link: http://pubs.rsc.org/en/content/articlelanding/2012/pp/c2pp25089f#!divAbstract

2011

24. Electron Donor–Acceptor Interactions with Flanking Purines Influence the Efficiency of Thymine Photodimerization
    Z. Pan, M. Hariharan, J. D. Arkin, A. S. Jalilov, M. McCullagh, G. C. Schatz, and F. D. Lewis*
    
    J. Am. Chem. Soc. 2011, 133, 20793–20798.
    Link: http://pubs.acs.org/doi/abs/10.1021/ja205460f
23. Conformation of a Dodecane DNA Hairpin Linker. Multiple Gauche Bonds Cover the Bases
    K. Siegmund, M. Hariharan, and F. D. Lewis*
    
    J. Phys. Chem. B, 2011, 115, 3740–3746.
    Link: http://pubs.acs.org/doi/abs/10.1021/jp201188f

2010

22. Hydrophobic Self-Assembly of a Perylenediimide-Linked DNA Dumbbell into Supramolecular Polymers
    P. Neelakandan, Z. Pan, M. Hariharan, Y. Zheng, F. D. Lewis*, H. Weissman, and B. Rybtchinski*
    
    J. Am. Chem. Soc. 2010, 132, 15808-15813.
    Link: http://pubs.acs.org/doi/abs/10.1021/ja1076525
21. Conformational Control of Thymine Photodimerization in Single-Strand and Duplex DNA Containing Locked Nucleic Acid TT Steps
    M. Hariharan, M. McCullagh, G. C. Schatz, and F. D. Lewis*
    
    J. Am. Chem. Soc. 2010, 132, 12856-12858.
    Link: http://pubs.acs.org/doi/abs/10.1021/ja106203q
20. Structure and Stability of Alkane-Linked DNA Hairpin Conjugates
    M. Hariharan,* K. Siegmund, and F. D. Lewis*
    
    J. Org. Chem. 2010, 75, 6236–6243.
    Link: http://pubs.acs.org/doi/abs/10.1021/jo1013299
19. Perylenediimide-Linked DNA Dumbbells: Long-Distance Electronic Interactions and Hydrophobic Assistance of Base-Pair Melting
    M. Hariharan, K. Siegmund, Y. Zheng, H. Long, G. C. Schatz, and F. D. Lewis*
    
    J. Phys. Chem. C 2010, 114, 20466–20471.
    Link: http://pubs.acs.org/doi/abs/10.1021/jp1048309
18. DNA Base-Pair Flipping with Fluorescent Perylenediimide Pincers
    T. A. Zeidan, M. Hariharan, K. Siegmund, and F. D. Lewis*
    
    Photochem. Photobiol. Sci. 2010, 9, 916-922.
    Link: http://pubs.rsc.org/en/content/articlelanding/2010/pp/c0pp00044b#!divAbstract
17. Conformational Control of TT-Dimerization in DNA Hairpins. A Molecular Dynamics Study
    M. McCullagh, M. Hariharan, F. D. Lewis*, D. Markovitsi, T. Douki and G. C. Schatz*
    
    J. Phys. Chem. B 2010, 114, 5215-5221.
    Link: http://pubs.acs.org/doi/abs/10.1021/jp100983t
16. Site-selective Interactions: Squaraine Dye-Serum Albumin Complexes with Enhanced Fluorescence and Triplet Yields
    V. S. Jisha, K. T. Arun, M. Hariharan and D. Ramaiah*
    
    J. Phys. Chem. B 2010, 114, 5912-5919.
    Link: http://pubs.acs.org/doi/abs/10.1021/jp100369x
15. Electron Hopping among Cofacially Stacked Perylenediimides Assembled Using DNA Hairpins
    T. M. Wilson, T. A. Zeidan, M. Hariharan, F. D. Lewis*, and M. R. Wasielewski*
    
    Angew. Chem. 2010, 49, 2385-2388.
    Link: http://onlinelibrary.wiley.com/wol1/doi/10.1002/anie.200907339/abstract
14. Direct Evidence on the External Stimuli Induced Dissembly of DNA through Microscopic Techniques
    M. Hariharan, E. Kuruvilla and D. Ramaiah*
    
    J. Phys. Chem. Lett. 2010, 1, 834-838.
    Link: http://pubs.acs.org/doi/10.1021/jz900447p
13. Photoinduced DNA Damage Efficiency and Cytotoxicity of Novel Viologen Linked Pyrene Conjugates
    M. Hariharan, D. Ramaiah*, I. Schulz, S. C. Karunakaran and B. Epe
    
    Chem. Comm. 2010, 46, 2064-2066.
    Link: http://pubs.rsc.org/en/Content/ArticleLanding/2010/CC/b924943e#!divAbstract

2009

12. Hydrophobic Dimerization and Thermal Dissociation of Perylenediimide-Linked DNA Hairpins
    M. Hariharan, Y. Zheng, H. Long, T. A. Zeidan, G. C. Schatz, J. Vura-Weis, M. R. Wasielewski, X. Zuo, D. M. Tiede, and F.. D. Lewis*
    
    J. Am. Chem. Soc. 2009, 131, 5920-5929.
    Link: http://pubs.acs.org/doi/abs/10.1021/ja900347t
11. Sum rules and determination of exciton coupling using absorption and circular dichroism spectra of biological polymers
    A. Burin, M. Armbruster, M. Hariharan and F. D. Lewis*
    Proc. Natl. Acad. Sci. USA 2009, 106, 989-984.
    Link: http://www.pnas.org/content/106/4/989

2008

10. Photoinduced Charge Separation in Pyrenedicarboxamide-linked DNA Hairpins,
    P. Daublain, K. Siegmund, M. Hariharan, J. Vura-Weis, M. R. Wasielewski, F. D. Lewis*, V. Shafirovich*, Q. Wang, M. Raytchev, and Torsten Fiebig*
    
    Photochem. Photobiol. Sci. 2008, 7, 1501-1508.
    Link: http://pubs.rsc.org/en/content/articlelanding/2008/pp/b813995d#!divAbstract
9. Context-Dependent Photodimerization in Isolated Thymine-Thymine Steps in DNA,
   M. Hariharan and F. D. Lewis*
   
   J. Am. Chem. Soc. 2008, 130, 11870-11871.
   Link: http://pubs.acs.org/doi/abs/10.1021/ja804950j

2007

8. Encapsulation of Electron Donor-Acceptor Dyads in b-Cyclodextrin Cavity: Unusual Planarization and Enhancement in Rate of Electron Transfer Reaction
   M. Hariharan, P. P. Neelakandan and D. Ramaiah*
   J. Phys. Chem. B, 2007, 111, 11940-11947.
   Link: http://pubs.acs.org/doi/abs/10.1021/jp074643d
7. Chiral supramolecular assemblies of a squaraine dye in solution and thin films: concentration-, temperature-, and solvent-induced chirality inversion
   K. Jyothish, M. Hariharan and D. Ramaiah*
   Chem. Eur. J. 2007, 13, 5944-5951.
   Link: http://onlinelibrary.wiley.com/wol1/doi/10.1002/chem.200700130/abstract
6. Selective Recognition of Tryptophan through the Inhibition of Intramolecular Charge-Transfer Interactions in an Aqueous Medium
   M. Hariharan, C. K. Suneesh and D. Ramaiah*
   
   Org. Lett. 2007, 9, 417-420.
   Link: http://pubs.acs.org/doi/abs/10.1021/ol062636m

2006

5. Novel Bifunctional Viologen-Linked Pyrene Conjugates: Synthesis and Study of their Interactions with Nucleosides and DNA
   M. Hariharan, J. Joseph and D. Ramaiah*
   J. Phys. Chem. B 2006, 110, 24678-24686.
   Link: http://pubs.acs.org/doi/abs/10.1021/jp063079o
4. A Supramolecular ON-OFF-ON Fluorescence Assay for Selective Recognition of GTP
   P. P. Neelakandan, M. Hariharan and D. Ramaiah*
   
   J. Am. Chem. Soc. 2006, 128, 11334-11335.
   Link: http://pubs.acs.org/doi/abs/10.1021/ja062651m
3. Site-Selective Binding and Dual Mode Recognition of Serum Albumin by a Squaraine Dye
   V. S. Jisha, K. T. Arun, M. Hariharan and D. Ramaiah*
   
   J. Am. Chem. Soc. 2006, 128, 6024-6025.
   Link: http://pubs.acs.org/doi/abs/10.1021/ja061301x

2005

2. Synthesis of a Novel Cyclic Donor-Acceptor Conjugate for Selective Recognition of ATP
   P. P. Neelakandan, M. Hariharan and D. Ramaiah*
   
   Org. Lett. 2005, 5765-5768.
   Link: http://pubs.acs.org/doi/abs/10.1021/ol052246k

LIST OF PATENTS

1. A Novel Cyclic Donor- Acceptor Conjugate, Process and a Supramolecular Fluorescent Marker Thereof
   D. Ramaiah, P. P. Neelakandan and M. Hariharan
   IN Patent No. 253901, dated August 31, 2012.