Dr Milan Kumar Bisai
Assistant Professor Grade I (Chemistry)
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  1. Łosiewicz, J., Bisai, M. K., Bub, Z. A., Macgregor, S. A.*, Ingleson, M. J.* Intermolecular Electrophilic Germylation Using GeCl4 and Al2Cl6. Angew. Chem. Int. Ed. 2026, 65, e7070836.

  2. Ajithkumar, V. S., Bisai, M. K., Ghanwat, P., Raj, K. V., Singh, G., Vanka, K. Sen, S. S.* Hypersilylsilylene Supported Ni(0) Toluene and Ni(II) Complexes with Catalytic Application. Organometallics 2025, 44, 2646–2653.

  3. Łosiewicz, J., Bisai, M. K., Nichol, G. S., Macgregor, S. A.*, Ingleson, M. J.* Transfer C−H Zincation and Borylation of Heteroarenes. Dalton Transactions 2025, 54, 16697–16703. (Hot article)

  4. Bisai, M. K., Łosiewicz, J., Nichol, G. S., Dominey, A. P., Thomas, S. P., Macgregor, S. A.*, Ingleson, M. J.* Ligand Non-innocence and an Unusual σ-bond Metathesis Step Enables Catalytic Borylation Using 9-borabicyclo-[3.3.1]-nonane. Chemical Science 2025, 16, 9255–9263.

  5. Ajithkumar, V. S., Bisai, M. K., Yuvaraj, K., Gonnade, R. G., Sen, S. S.* Sila[1]ferrocenophanes with Bulky Substituents. Eur. J. Inorg. Chem. 2025, 28, e202500120.

  6. Bisai, M. K., Łosiewicz, J., Sotorrios, L., Nichol, G. S., Dominey, A. P., Cowley, M. J., Thomas, S. P., Macgregor, S. A.*, Ingleson, M. J.* Transition Metal-Free Catalytic C−H Zincation and C−H Alumination. Angew. Chem. Int. Ed. 2024, 136, e202404848. (Hot paper, Highlighted in ChemistryViews)

  7. Grundy, M. E., Sotorrios, L., Bisai, M. K., Yuan, K., Macgregor, S. A.*, Ingleson, M. J.* Understanding and Expanding Zinc Cation/Amine Frustrated Lewis Pair Catalyzed C−H Borylation. ACS Catalysis 2023, 13, 2286–2294.

  8. Bisai, M. K., Ajithkumar, V. S., Raj, K. V., Vanka, K., Gonnade, R. G., Sen, S. S.* A Zwitterionic Disilanylium from an Unsymmetric Disilene. Chemical Communications 2023, 59, 1669–1672.

  9. Gour, K., Bisai, M. K., Sen, S. S.* Hypersilyl Substituent in Heavier Low-valent Group 14 Chemistry. Eur. J. Inorg. Chem. 2022, e202200071, 1–14. (Invited review article)

  10. Kumar, R., Bisai, M. K., Jain, S., Vanka, K., Sen, S. S.* Deoxygenative Hydroboration of Primary and Secondary Amides: A Catalyst- and Solvent-Free Approach. Chemical Communications 2021, 57, 10596–10599.

  11. Bisai, M. K., Das, T., Vanka, K., Gonnade, R. G., Sen, S. S.* Unsymmetrical sp2-sp3 Disilenes. Angew. Chem. Int. Ed. 2021, 60, 20706–20710. (Hot paper)

  12. Bisai, M. K., Gour, K., Das, T., Vanka, K., Sen, S. S.* Readily Available Lithium Compounds as Catalysts for the Hydroboration of Carbodiimides and Esters. Journal of Organometallic Chemistry 2021, 949, 121924.

  13. Bisai, M. K., Ajithkumar, V. S., Gonnade, R. G., Sen, S. S.* Access to a Variety of Ge(II) and Sn(II) Compounds through Substitution of Hypersilyl Moiety. Organometallics 2021, 40, 2651–2657.

  14. Bisai, M. K., Sharma, V., Gonnade, R. G., Sen, S. S.* Reactivities of Silaimines with Boranes: From Cooperative B−H Bond Activation to Donor Stabilized Silyl Cation. Organometallics 2021, 40, 2133–2138.

  15. Dixit, R., Bisai, M. K., Yadav, S., Yadav, V., Sen, S. S.*, Vanka, K.* Substrate, Catalyst and Solvent: The Triune Nature of Multitasking Reagents in Hydroboration and Cyanosilylation. Organometallics 2021, 40, 1104–1112.

  16. Kundu, G., Ajithkumar, V. S., Bisai, M. K., Tothadi, S., Das, T., Vanka, K., Sen, S. S.* Diverse Reactivity of Carbenes and Silylenes towards Fluoropyridines. Chemical Communications 2021, 57, 4428–4431.

  17. Bisai, M. K., Gour, K., Das, T., Vanka, K., Sen, S. S.* Lithium Compound Catalyzed Deoxygenative Hydroboration of Primary, Secondary and Tertiary Amides. Dalton Transactions 2021, 50, 2354–2358.

  18. Bisai, M. K., Swamy, V. S. V. S. N., Raj, K. V., Vanka, K., Sen, S. S.* Diverse Reactivity of Hypersilylsilylene with Boranes and Three-Component Reactions with Aldehyde and HBpin. Inorganic Chemistry 2021, 60, 1654–1663.

  19. Bisai, M. K., Yadav, S., Das, T., Vanka, K., Sen, S. S.* Lithium Compounds as Single Site Catalyst for Hydroboration of Alkenes and Alkynes. Chemical Communications 2019, 55, 11711–11714.

  20. Bisai, M. K., Swamy, V. S. V. S. N., Das, T., Vanka, K., Gonnade, R. G., Sen, S. S.* Synthesis and Reactivity of a Hypersilylsilylene. Inorganic Chemistry 2019, 58, 10536–10542.

  21. Yadav, S., Dixit, R., Bisai, M. K., Vanka, K.*, Sen, S. S.* Alkaline Earth Metal Compounds of Methylpyridinato β-Diketiminate Ligands and Their Catalytic Application in Hydroboration of Aldehydes and Ketones. Organometallics 2018, 37, 4576–4584.

  22. Bisai, M. K., Das, T., Vanka, K., Sen, S. S.* Easily Accessible Lithium Compound Catalyzed Mild and Facile Hydroboration and Cyanosilylation of Aldehydes and Ketones. Chemical Communications 2018, 54, 6843–6846.

  23. Swamy, V. S. V. S. N., Bisai, M. K., Das, T., Sen, S. S.* Metal Free Mild and Selective Aldehyde Cyanosilylation by a Neutral Penta-coordinate Silicon Compound. Chemical Communications 2017, 53, 6910−–6913.

  24. Bisai, M. K., Pahar, S., Das, T., Vanka, K.*, Sen, S. S.* Transition Metal Free Catalytic Hydroboration of Aldehydes and Aldimines by Amidinato Silane. Dalton Transactions 2017, 46, 2420–2424.

‡ = Equal contribution, * = Corresponding author