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Indian Institute of Science Education and Research
Thiruvananthapuram

Dr Vinayak B. Kamble
Associate Professor (Physics)
  +91 (0)471 - +91-471-2778056
  a2J2aW5heWFrQGlpc2VydHZtLmFjLmlu

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Patent

Patent Application No: 202441022068; Filing date: 22/03/2024

Title: “HYDROGEN GAS SENSING SYSTEM, METHOD OF ITS FABRICATION AND SENSING”                    

Applicant: Indian Institute of Science Education and Research Thiruvananthapuram

Investigators : Silpa S., Nidha M., Kritika Sharu, J. Mitra and Vinayak Kamble

Status: Granted. 31st Dec 2024.

 

Journal Publications

  1. Mohammed Salman C K; Muskan Beura; Archana Singh; Anil Dahuja, Vinayak B. Kamble, Rajendra Prasad Shukla and Veda Krishnan Biomimic Models for In Vitro Glycemic Index: Scope of Sensor Integration and Artificial Intelligence, Food Chemistry X, just Accepted 2024.
  2. Dharsana P. D., Sheetal Kathayat Bisht, Saptak Majumder, Dipanjana Mondal, Pintu Singha, Gaurav G. Bolegave, Vinayak B. Kamble, Ajay Venugopal*, Bi[Se-(2-Me2NC6H4)]3: Single Source Precursor for Preparing Pure-Phase, 2-Dimensional Bismuth Selenide Films, European Journal of Inorganic Chemistry, e202400762, 2024.
  3. Soumya Biswas, Keshav Dabral, Saptak Majumder, Rajasekhar Parsuraman and Vinayak Kamble. Predicting of the realizable maximum power factor using the Jonker and Ioffe formulation: Al-doped ZnO Triangular microcrystals with graphite inclusion case study. ACS Applied Energy Materials, 7 (19), 8991-9002, 2024.
  4. Tathagata Sarkar, Soumya Biswas, Sonali Kakkar, A. V. Raghu, S. D. Kaushik, Chandan Bera, Vinayak B. Kamble* Coexistence of Multiple Magnetic Interactions in Oxygen Deficient V2O5 Nanoparticles. Journal of Physics: Condensed Matter, 36, 495803, 2024.
  5. Abin Tom, D. K. Singh, V. K. Shaw, Abhijith P. V., Sajana S., Kirandas P.S., Viney Dixit, Vinayak Kamble, S. P. Pai, and D. Jaiswal-Nagar*, Feedback based gas sensing setup for ppb to ppm level sensing, Review of Scientific Instruments, 95, 085003, 2024.
  6. Shivam Singh, Sajana S, Purnima, Gajje Sreelekha, Chandranath Adak, Rajendra P. Shukla, and Vinayak Kamble*. Metal Oxide-based Gas Sensor Array for the VOCs Analysis in Complex Mixtures using Machine Learning. Microchimica Acta. 191, 196, 2024.
  7. Soumya Biswas, Noora Naushad, Kalyani S, Vinayak B. Kamble*, Resistive Avalanches in La1-xSrxCoO3-δ (x = 0, 0.3) thin films and its reversible evolution by tuning lattice oxygen vacancies (δ), ACS Materials Au 4, 2024.
  8. Tathagata Sarkar, Saptak Majumder, Soumya Biswas, Sona S Rose, Vinayak B. Kamble*, Engineering Lattice Oxygen defects and Polaronic transport in Vanadium pentoxide via isovalent phosphorous doping, Applied Physics Letters, 123, 222106, 2023.
  9. Silpa S., Srinivas G., Arup Biswas, Harish C. Barshilia, Vinayak B. Kamble*, Realizing Optical Micro-cavity in CuCo2O4-W-CuCo2O4 thin film stack for Spectrally Selective Solar Absorbers. Advanced Optical Materials 2300567, 2023.
  10. Abhijith PV, Abin Tom, Kusuma Urs, K N Prajapati, Sajana S, J Mitra, Deepshikha Jaiswal-Nagar, Vinayak Kamble* Frequency dependent Impedance Response Analysis of Nanocrystalline ZnO Chemiresistors, Nanotechnology, 34, 365501, 2023.
  11. Arghya Dutta, Abhinandan Mahanta, Subhra Jyoti Panda, Soumya Biswas, Vinayak B Kamble, Chandra Shekhar Purohit, SK Jasimuddin, Rajarshi Ghosh*, Synthesis, X-ray structural characterization, and electrochemical investigations on a semiconducting Ni (II) dithiolate with tris (1, 10-phenanthroline) nickel (II) as counter-cation. Journal of Chemical Sciences 135 (3), 62, 2023.
  12. Anakha Anson, Dipanjana Mondal, Varsha Biswas, Kusuma Urs MB, Vinayak Kamble, Suppressed Polaronic Conductivity induced Sensor Response enhancement in Mo doped V2O5 Nanowires, Journal of Applied Physics. 133, 194505, 2023.
  13. Jyothish Raj, Soumya Biswas, Vinayak Kamble*, Crossover from small polaron tunneling to correlated barrier hopping and its evolution with thermal instability of SnO surface, Applied Surface Science, 624, p.157078, 2023.
  14. Arghya Dutta, Sanjay Mondal, Soumya Biswas, Vinayak B Kamble, Shubhamoy Chowdhury and Rajarshi Ghosh*, Synthesis, spectroscopic characterization and solid-state electrical behavior of [Ni(L)2](L=bis(1,2-di(4-methoxyphenyl)ethene-1,2-dithiolate)): A computational investigation on UV-Vis-NIR absorption and electrical transport. Journal of Coordination Chemistry, 76.5-6, 771-782, 2023.
  15. Sourav Biswas, Anish Kumar Das, Arthur C. Reber, Soumya Biswas, Subhrajyoti Bhandary, Vinayak B.  Kamble, Shiv N. Khanna, Sukhendu Mandal*, A new Ag-S Cluster [Ag50S13(StBu)20][CF3COO]4 with its Unique hcp Ag14 Kernel and Ag36 Keplerian Shell-based Structural Architecture and its Photoresponsivity, Nano Letters, 22, 9, 3721–3727, 2022.
  16. P. Manju, Ashna Babu, Sruthy S. P., Dumpala Tirumalarao, Abhijith P.V., Vinayak B. Kamble, D. Jaiswal-Nagar*, Variation of citrate to metal cation ratio for dense and phase pure BaZrO3 via auto-combustion synthesis, Journal of the American Ceramic Society 105(8), 5082-5101, 2022.
  17. Jishnu V, Shashank Mishra, Kusuma MB, Sanchu Thomas, Chandra Shekhar Tiwary, Krishanu Biswas, Vinayak B Kamble, Highly Sensitive and Selective Triethylamine Sensing through High Entropy Alloy (Ti-Zr-Cr-V-Ni) Nanoparticles induced Fermi Energy Control of MoS2 Nanosheets ACS Applied Materials and Interfaces, 14, 11, 1–13664, 2022.
  18. Kusuma MB Urs, Krutikesh Sahoo, Navakanta Bhat, Vinayak Kamble, Complementary Metal Oxide Semiconductor-Compatible Top-Down Fabrication of a Ni/NiO Nanobeam Room Temperature Hydrogen Sensor Device, ACS Applied Electronic Materials, 4, 1, 87–91, 2022.
  19. Adithya Jayakumar, Viney Dixit, Sarath Jose, Praveen S. G., Vinayak B. Kamble, and D. Jaiswal-Nagar*, Charge transport variation from Bloch-Grüneisen to Mott variable range hopping and transport change due to hydrogenation in Palladium thin films, Scientific Reports, 11, 22298, 2021.
  20. Kusuma Urs MB, Vinayak B Kamble. Protonic Conduction Induced Selective Room Temperature Hydrogen Response in ZnO/NiO Heterojunction Surfaces. Sensors and Actuators B: Chemical, 348 (12), 130605, 2021.
  21. Arghya Dutta, Arnab Chatterjee, Tathagata Sarkar, Vinayak B Kamble*, Rajarshi Ghosh*, Synthesis, structural characterization and variable temperature electrical conductivity of a pentanuclear Pd(II) dithiolato complex. Inorganic Chemistry Communications. 133, 108889, 2021.
  22. Soumya Biswas, Saurabh Singh, Shubham Singh, Shashwata Chattopadyay, K. Kanishka H. De Silva, M. Yoshimura, J. Mitra, Vinayak B Kamble *, Selective Enhancement in Phonon Scattering leads to High Thermoelectric Figure of Merit in Graphene Oxide encapsulated ZnO nanocomposites, ACS Applied Materials and Interfaces, 13 (20), 23771–23786 2021.
  23. Soumya Biswas, Aditya Dutt, Nirmal Sebastian and Vinayak B Kamble*, Simple, Reversible Gradient Seebeck Coefficient Measurement System for 300 – 600 K with COMSOL simulations, Review of Scientific Instruments, 92 (4), 044903, 2021.
  24. Christina Antony, Praveen S.G., Adithya Jayakumar, Gaana K., Akshay Yadav, Nikhil Sivakumar, Niranjan Kamath, Suma M. N., Vinayak Kamble and Deepshikha Jaiswal-Nagar*, Polyvinylpyrrolidone-Stabilized Palladium Nanocrystals as Chemiresistive Sensors for Low Concentration Hydrogen Detection, ACS Applied Nanomaterials, 4(2), 1643–1653, 2021.
  25. Kusuma Urs MB and Vinayak B Kamble*, Surface Photovoltage Response of Zinc Oxide Microrods on prismatic planes: Effect of UV, Temperature and Oxygen ambience, Journal of Materials Science: Materials in Electronics, 32, 6414–6424, 2021
  26. Soumya Biswas, Madhujith M K and Vinayak B Kamble *, Proof-of-concept thermoelectric oxygen sensor exploiting oxygen mobility of GdBaCo2O5+δ, Journal of Applied Physics, 129, 5, 054502, 2021.
  27. Dharmendra K. Singh, Praveen S. G., Adithya Jayakumar, Vinayak B Kamble, J. Mitra, and D. Jaiswal-Nagar*, Thickness induced metal to insulator charge transport and unusual hydrogen response in granular palladium nanofilms, Physical Chemistry Chemical Physics, 22, 27861-27872, 2020.
  28. Parikshit Moitra, Deepa Bhagat, Vinayak B. Kamble, Arun M.Umarji, Rudra Pratap, Santanu Bhattacharya*, First example of engineered β-cyclodextrinylated MEMS devices for volatile pheromone sensing of olive fruit pests, Biosensors and Bioelectronics, 173, 112728, 2020.
  29. Shubham Yadav, Archa Nair, Kusuma Urs MB, and Vinayak B Kamble*, Protonic Titanate Nanotube–Reduced Graphene Oxide Composites for Hydrogen Sensing, ACS Applied Nanomaterials, 3(10) 10082–10093, 2020.
  30. Nithin P, Kusuma Urs MB, Sukhendu Mandal and Vinayak B Kamble*, Underpinning the Conductivity Mechanism in Wide Bandgap Metal Organic Framework through Chemical Sensing, AIP Advances, 10, 085105, 2020.
  31. Kusuma Urs MB, Nirmal Katiyar, Ritesh Kumar, Abhishek Singh, Krishanu Biswas, C S Tiwary and Vinayak Kamble*: Multi-component (Ag-Au-Cu-Pd-Pt) Alloy Nanoparticles Decorated p-type 2D-Molybdenum Disulphide (MoS2) for Enhanced Hydrogen Sensing, Nanoscale, 12, 11830-11841, 2020.
  32. Anjana James, Prajisha P, Harish Barshilia, Vinayak Kamble*, Effect of surface roughness on the solar photothermal conversion efficiency of spray-coated CuCo2O4 films. Journal of Applied Physics 127 (14), 145303, 2020.
  33. Manju P., Neeraj Rajak, Alex Andrews, Vinayak Kamble, Deepshikha Jaiswal-Nagar*: Orthorhombic crystal structure and oxygen deficient cluster distribution model for YBa2Cu3-xAlxO6+δ superconductor.”, Scientific Reports, 10 (1), 1-13, 2020.
  34. Sreya Suresh, Kusuma Urs., Anupama T. Vasudevan, Sharath Sriram, Vinayak Kamble*, Analysis of unusual and instantaneous overshoots in response transients of gas sensors, Physica Status Solidi RRL, 13: 1800683, 2019.
  35. Vinayak Kamble*, Facile and in-situ Spray Deposition of SnO2 – Reduced Graphene Oxide Heterostructure Sensor devices, Journal of Physics communications, 3 (1), 011001, 2019.
  36. Kusuma URS, S V Bhat, Vinayak Kamble*: On exceeding the solubility limit of Cr+3 dopants in SnO2 nanoparticles based Dilute Magnetic Semiconductors, Journal of Applied Physics, 123, 161518, 2018.
  37. Sukanti Behera, Vinayak Kamble, S Vitta, A Umarji*, C Shivakumara: Synthesis, structure and thermoelectric properties of La1-xNaxCoO3 perovskite oxides, Bulletin of Materials Science, 40, 1291, 2017.
  38. Vinayak Kamble*, Arun M. Umarji: Achieving selectivity from the synergistic effect of Cr and Pt activated SnO2 thin film Gas Sensors. Sensors and Actuators B: Chemical 236, 208, 2016.
  39. Srinatha N, Y S No, Vinayak Kamble, Sujay Chakravarty, Suriya Murthy, Basavaraj Angadi, A. M. Umarji, Won-Kook Choi: Effect of RF power on the structural, optical and gas sensing properties of RF-sputtered Al doped ZnO thin films. RSC Advances 6, 9779, 2016.
  40. Seema Joshi, Vinayak Kamble, Manoj Kumar, A.M. Umarji, Geetika Srivastava: Nickel Substitution Induced Effects on Gas Sensing Properties of Cobalt Ferrite Nanoparticles. Journal of Alloys and Compounds 654, 460, 2016.
  41. Vinayak Kamble*, Arun M. Umarji: Effect of Pt doping on Gas Sensing properties of porous Chromium Oxide films through Kinetic Response Analysis Approach. RSC Advances 5, 27509, 2015.
  42. Vinayak Kamble*, Arun Umarji: Analyzing the kinetic response of tin oxide-carbon and tin oxide-CNT composites gas sensors for alcohols detection. AIP Advances 5, 037138, 2015.
  43. Vinayak Kamble*, Arun M. Umarji: Correlating defect induced ferromagnetism and gas sensing properties of undoped tin oxide sensors. Applied Physics Letters 104, 251912, 2014.
  44. Vinayak Kamble*, Arun M. Umarji: Defect induced optical bandgap narrowing in undoped SnO2 nanocrystals. AIP Advances 3, 082120, 2013.
  45. Vinayak Kamble*, S. V. Bhat, A. M. Umarji: Investigating thermal stability of structural defects and its effect on d0 ferromagnetism in undoped SnO2. Journal of Applied Physics 113, 244307, 2013.
  46. Vinayak Kamble*, Arun M. Umarji: Gas sensing response analysis of p-type porous Chromium Oxide thin films. Journal of Materials Chemistry C 01, 8167, 2013.

Book chapters

  1. Rohini Bhalerao-Panajkar, A. D. Sheikh and Vinayak Kamble and Sulabha K Kulkarni, Size, shape and structure tuned metal, metal-oxide and hybrid nanomaterials for ultra-sensitive gas sensors. Handbook of Materials Science Editors: R. S. Ningthoujam and A. K. Tyagi 2023 Publisher: Springer Nature. (Just accepted)
  2. Role of point defects in gas sensing effects of metal oxides, Vinayak Kamble, Book Title: Metal Oxide Defects: Fundamentals, Design, Development and Applications, Publisher Elsevier, Editors: Vijay Kumar, Sudipta Som, Vishal Sharma, Hendrik C Swart,, 2022 just accepted.
  3. Reduced graphene oxide photodetector devices for infra-red sensing, Vinayak Kamble, Soumya Biswas, Appu VR, Arun Kumar, Book title:  Carbon Nanomaterial Electronics: Devices and Applications, Publisher Spinger, Editors: Rupam goswami and Arnab Hazra, pp 349-369, 2021.
  4. Nanocrystalline Oxides as alternative materials for spectrally selective solar absorber coatings, Vinayak Kamble, Soumya Biswas and Dhruv M. Book title: Nano Tools & Devices for Enhanced Renewable Energy, Publisher Elsevier, Editors: Sheila Devasahayam and Chaudhery Mustansar Hussain, 447-472, 2020.

 

ArXive Preprints

  1. Shivam Singh, Gajje Sreelekha, Chandranath Adak, Rajendra P. Shukla, and Vinayak Kamble. "Metal Oxide-based Gas Sensor Array for the VOCs Analysis in Complex Mixtures using Machine Learning." (arXiv:2307.06556) 2023.
  2. High Entropy Alloy Nanoparticles Decorated, p-type 2D-Molybdenum Disulphide (MoS2) and Gold Schottky Junction Enhanced Hydrogen Sensing KU MB, NK Katiyar, R Kumar, K Biswas, AK Singh, CS Tiwary, V Kamble (arXiv preprint arXiv:2002.02366) 2020.
  3. Simple, Reversible Gradient Seebeck Coefficient Measurement System for 300-600 K, Soumya Biswas, Aditya Dutt, Nirmal Sabastian and Vinayak Kamble* (arXiv preprint arXiv:1908.05636) 2020.
  4. Proof-of-concept thermoelectric oxygen sensor exploiting oxygen mobility of GdBaCo2O5+δ, Soumya Biswas, Madhujith M K and Vinayak Kamble*, (arXiv Preprint arXiv:2010.01783) 2020.
  5. Thickness induced metal to insulator charge transport and unusual hydrogen response in granular palladium nanofilms, DK Singh, A Jayakumar, VB Kamble, J Mitra, D Jaiswal-Nagar (arXiv preprint arXiv:2011.05123) 2020.
  6. Metal-polymer hybrid chemiresistive sensor for low concentration fast hydrogen detection, Christina E Antony, Adithya Jayakumar, Akshay Yadav, Nikhil S Sivakumar, Niranjan Kamath, Vinayak B Kamble, D Jaiswal-Nagar. (arXiv preprint arXiv:2011.07599)2021.
  7. Selective Enhancement in Phonon Scattering leads to High Thermoelectric Figure of Merit in ZnO -- Graphene Oxide Core-shell Nanohybrids, Soumya Biswas, Saurabh Singh, Shubham Singh, Shashwata Chattopadhyay, K. K. H. De Silva, M. Yoshimura, J. Mitra, Vinayak Kamble (arXive Preprint arXiv:2102.01896) 2021.
  8. Protonic Conduction Induced Selective Room Temperature Hydrogen Response in ZnO/NiO Heterojunction Surfaces. Kusuma Urs MB, Vinayak B Kamble. (arXiv preprint arXiv:2102.04853) 2021. 
  9. Shivam Tyagi, Shubham Yadav, Vaibhav Wani, Shivam Singh, Soumya Biswas, Krishna Nand Prajapati, Vinayak Kamble*, CVD Growth of Tin Selenide Thin Films for Optoelectronic Applications,

 

Conference Proceedings

  1. Sandesh Surendra Chougule, Gaurav Bolegave, Bhaskar Soni, Vinayak Kamble, Christos N. Markides, An Investigation of the Synthesis and Optical Properties of Novel Ag/ZnO Hybrid Nanofluids for Spectral Splitting in Photovoltaic-Thermal Systems, 36th International Conference on Efficiency, Cost, Optimization, Simulation and Environmental Impact of Energy Systems (ECOS 2023) https://doi.org/10.52202/069564-0158
  2. Shivam Tyagi, Shubham Yadav, Vaibhav Wani, Shivam Singh, Soumya Biswas, Krishna Nand Prajapati, Vinayak Kamble*, CVD Growth of Tin Selenide Thin Films for Optoelectronic Applications, IEEE proceedings of The IEEE Region 10 Symposium (TENSYMP) 2022.
  3. Archa Nair and Vinayak Kamble*, Large area coverage and Controlled Photoluminescence from vertically aligned ZnO nanorods on Cu substrates, Materials Today proceedings, 47, 5223-5227, 2021.
  4. Aditya S Dutt, Soumya Biswas, Keshav Dabral, Rajasekar P and Vinayak Kamble*, High Thermoelectric Figure of Merit of Aluminum doped Zinc Oxide through Unintentional Graphite Inclusion, AIP conference proceedings, 2297 (1), 020005, 2020. 
  5. Vinayak Kamble*, A. M. Umarji: Chromium oxide thin films by Ultrasonic Nebulized Spray Pyrolysis of Aqueous Combustion Mixture for gas sensing application. IEEE Proceedings of International symposium on physics and technology of sensors; 03/2012.